Four men, three women, a teenage boy and girl, and a young child were killed, Gardaí said this afternoon.
The explosion happened at an Applegreen service station in the village of Creeslough on Friday afternoon.
Eight people are in hospital, one is critically ill. Police said their information so far pointed towards a tragic accident.
The blast destroyed the building and a section of an apartment building.
Emergency services held a moment’s silence in memory of those killed during a press conference on Saturday afternoon.
Although police remain at the scene, they do not expect to find anyone else.
Creeslough is a small village is about 15 miles from Letterkenny and 30 miles from the border with the North. It has a population of about 400 people.
Garda Supt David Kelly described the explosion as a tragedy for the community which has left families devastated.
He paid tribute to those killed and praised emergency services who assisted them from Donegal and Northern Ireland.
“That is what it is to be in Donegal, we look out for each other,” he said.
“Forgive me if I get a bit emotional, you’re dealing with the public you know.
“But I would say in terms of what we did … at this point in this time we have to keep an open mind as a police service in how we are investigate this.“Our information at this point in time is pointing towards a tragic accident. That said, being a Garda, I have to take a holistic and overall viewpoint but that’s where we’re going at the moment.”
Garry Martin, director of emergency services for Donegal County Council, said 65 fire service personnel were dispatched to the scene across Friday and Saturday.
“Our primary focus yesterday was to lead on the search and recovery of the injured and to stabilise what was a substantially-damaged building including many displaced and broken concrete slabs,” he said.
JJ McGowan, chief ambulance officer in the western region, confirmed one of the eight people injured in the explosion is in a critical condition and has been taken to a Dublin hospital.
The seven others are stable in Letterkenny hospital.
“The National Ambulance Service allocated a total of eight emergency ambulances yesterday and three this morning,” Mr McGowan said.
From 12 noon local time, counselling and other services were put in place at Creeslough Community Day Care Centre.
Earlier, the Taoiseach Micheál Martin, said it was an “unspeakable tragedy”.
“The entire nation is shocked at what has happened,” he said.
Mr Martin made a special mention of the fire and emergency crews from Northern Ireland who, he said, came quickly and willingly to help.
“That will be long remembered… that solidarity and that sense of strong community between the essential services.”
The founder and chief executive of Applegreen, Joe Barrett, said Friday was a “very dark day for Creeslough, for Donegal, for Ireland” and the wider Applegreen family.
“This is a hugely tragic event, and I would like to offer our deepest sympathies to the families and friends of the deceased, and to the entire community in Creeslough,” Mr Barrett said.
“We are utterly shocked and saddened at what happened yesterday.”
The local church in Creeslough held Mass on Saturday morning for the community.
Father John Joe Duffy told the congregation that their community has been hit by “a tsunami of grief”.
Catholic Bishop Alan McGuckian has visited the Co Donegal village.
Describing the “darkest day in Donegal”, he urged all parishes in the diocese of Raphoe to come together to pray at Mass this weekend.
“Last night I went to Creeslough to offer pastoral support. I met and prayed with family members who are in terrible shock and pain,” he said.
“I have witnessed at first hand the immediate reaction of the local community to the tragedy who, in their bravery, took risks at the site to help others even to the detriment of their own safety.
Local Sinn Féin politician Pearse Doherty said the community in Creeslough “will be forever changed”.“It has affected so many and it has been said how close-knit this community is,” Mr Doherty said.
“The community is just in shock, we’re just numb and there are broken hearts all over.
“There are many people in this community that will see wakes and funerals… and that trauma is going to last a long time. ”
PSNI Chief Constable Simon Byrne tweeted on Saturday morning to pay tribute to those dealing with the tragedy.
Liam McElhinney, chairperson of the local Gaelic Athletic Association club in Creeslough, Naomh Michaeál, said he had visited the shop a short while before the incident.
“I was in shock when the news came through. I myself had just left the shop at half two so it just shows you could be in the wrong place at the wrong time,” he said.
“Some of the people that have died are known personally by myself and it’s very hard to watch.
“It could have been any of us… it’s a massive thing to happen in our community and it’ll take a long time to get over it.”
Meanwhile, President Michael D Higgins said his thoughts and prayers were with those who have lost their lives, and their families.
In a statement, President Higgins said: “May I, as president, express what I know will be the shock shared by all people throughout the country on learning of the terrible tragedy which has unfolded in Creeslough, County Donegal.”
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